cis-Conformation of indigo in the coordination complex (indigo-O,O)(Cp*CrIICl)
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چکیده
منابع مشابه
cis-Conformation of indigo in the coordination complex (indigo-O,O)(Cp*CrIICl).
The interaction of decamethylchromocene (Cp*2Cr) with indigo in the presence of a Cl- source yields the coordination complex (indigo-O,O)(Cp*CrIICl) (1) in which one Cp* ligand at chromium is substituted by indigo. Indigo adopts an unusual cis-conformation in 1, allowing the coordination of both indigo carbonyl groups to one CrII center. Complex 1 contains CrII with an S = 1 spin state and indi...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2016
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c6dt03545k